tert-Butyl hydroperoxide → HCID 15570269, compound

HRID 1263073Notes

Reaction equation

HRID 1263073 reaction equation
[C:1]([O:5][OH:6])([CH3:4])([CH3:3])[CH3:2].[C:7](Cl)(=[O:11])[C:8]([Cl:10])=[O:9]>>[C:1]([O:5][O:6][C:7](=[O:11])[C:8]([Cl:10])=[O:9])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 6410tert-Butyl hydroperoxideHCID 65578Oxalyl chloride

Product 1

HCID 15570269HCID 15570269, compound

Conditions

Temperature
0 °C

Procedure

A solution of tert-butyl hydroperoxide (9.0 g; 0.1 mole) in petroleum spirit (80 ml) was added dropwise over a period of 1 hour to a stirred solution of oxalyl chloride (25.4 g; 0.2 mole) in petroleum spirit (80 ml) at a temperature of 0° C. On completion of the addition the reaction mixture was stirred for a further 3 hours at a temperature of 0° C. The solvent and excess oxalyl chloride were evaporated under reduced pressure at ice bath temperature to give tert-butylperoxyoxalyl chloride as a colourless oil (16.6 g; 92%) suitable for use in further preparations.

Workup

  1. additionOn completion of the addition the reaction mixture
  2. customThe solvent and excess oxalyl chloride were evaporated under reduced pressure at ice bath temperature

Sources & evidence

ORD record
ord-c9488592072842a196b552bcb5d356ed
Source dataset
uspto-grants-1984_06
Patent number
US04455412

Reaction notes

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