Diethyl Malonate → Ethyl 2-(4,4,5,5,6,6,7,7,7-nonafluoroheptyl)-9-decenoate

HRID 1267480Notes

Reaction equation

I[CH2:2][CH2:3][CH2:4][C:5]([F:17])([F:16])[C:6]([F:15])([F:14])[C:7]([F:13])([F:12])[C:8]([F:11])([F:10])[F:9].[C:18](OCC)(=O)[CH2:19][C:20]([O:22][CH2:23][CH3:24])=[O:21].Br[CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]=C>>[F:16][C:5]([F:17])([C:6]([F:15])([F:14])[C:7]([F:13])([F:12])[C:8]([F:11])([F:10])[F:9])[CH2:4][CH2:3][CH2:2][CH:19]([CH2:18][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH:31]=[CH2:30])[C:20]([O:22][CH2:23][CH3:24])=[O:21]

Participants

Reactant 3

HCID 7761Diethyl Malonate

HCID 759078-Bromooct-1-ene

HCID 120167744,4,5,5,6,6,7,7,7-Nonafluoroheptyl iodide

Product 1

HCID 22718049Ethyl 2-(4,4,5,5,6,6,7,7,7-nonafluoroheptyl)-9-decenoate

Procedure

Starting with the 1-iodo-4,4,5,5,6,6,7,7,7-nonafluoroheptane prepared in Example 1, diethyl malonate and 8-bromooct-1-ene, a procedure analogous to that as shown in Example 3, 4 or 5 was repeated to give ethyl 2-(4,4,5,5,6,6,7,7,7-nonafluoroheptyl)-9-decenoate.

Sources & evidence

ORD record: ord-7677d2d6dfbb43e78ee5372a0b5cde4b
Source dataset: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06552069B1

Reaction notes

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