Citric Acid → HCID 178518214, compound
Reaction equation
C[C@@H]1O[C@@H](O[C@H]2[C@H](OC3C=C(O)C(C(CCC4C=CC(OC)=C(O)C=4)=O)=C(O)C=3)O[C@H](CO)[C@@H](O)[C@@H]2O)[C@H](O)[C@H](O)[C@H]1O.OC[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.C(O)(=O)CC(CC(O)=O)(C(O)=O)O.C(O)(=O)C(CC(O)=O)O.[C@@H]1(N2C3N=CN=C(O)C=3N=C2)O[C@H](C(C([O-])=O)O)[C@@H](O)[C@H]1O.[Na+:100].[Na+].[C@@H]1(N2C3N=CN=C(O)C=3N=C2)O[C@H](C(C([O-])=O)O)[C@@H](O)[C@H]1O.[CH:124]1[N:128]([C@@H:129]2[O:133][C@H:132]([CH2:134][O:135][P:136]([O-:139])([O-:138])=[O:137])[C@@H:131]([OH:140])[C@H:130]2[OH:141])[C:127]2[NH:142][C:143](N)=[N:144][C:145](=[O:146])[C:126]=2[N:125]=1.[Na+].[Na+]>O>[CH:143]1[NH:142][C:127]2[N:128]([C@@H:129]3[O:133][C@H:132]([CH2:134][O:135][P:136]([O-:139])([O-:138])=[O:137])[C@@H:131]([OH:140])[C@H:130]3[OH:141])[CH:124]=[N:125][C:126]=2[C:145](=[O:146])[N:144]=1.[Na+:100].[Na+:100]Participants
Procedure
Neohesperidin dihydrochalcone (10 g) and sorbitol (50 g) were mixed together and were heated to 140° C. to 170° C. (water or alcohol in appropriate quantities may be used to assist dissolution of the starting material). The liquified mixture was cooled to about 60° C. to 70° C., and the pH of the solution was adjusted to 5.5 to 6.0 by the addition of citric acid or malic acid. Then a mixture of disodium 5'--inosinate and disodium 5'--guanylate (0.016 g), which is commercially obtained as ribotide, was added and the entire mixture was dried by conventional methods. The dried mixture was ground into a fine powder. The resulting composition had excellent solubility in aqueous solution and gave an immediate sweet taste with no methanol-like aftertaste. This composition may be used to sweeten beverages and other food products.
Workup
- dissolutiondissolution of the starting material)
- temperatureThe liquified mixture was cooled to about 60° C. to 70° C.
Sources & evidence
- ORD record
- ord-ce44b1806a0949bbbe4a6081be05a341
- Source dataset
- uspto-grants-1981_03
- Patent number
- US04254155
Reaction notes
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