Ethyl Bromide → HCID 73013555, compound

HRID 1272114Notes

Reaction equation

HRID 1272114 reaction equation
[CH3:1][CH2:2][O:3][C:4]([C:6]1[N:16]([C:17]([O:19][C:20]([CH3:23])([CH3:22])[CH3:21])=[O:18])[C:9]2=[N:10][C:11]([Br:15])=[C:12]([OH:14])[CH:13]=[C:8]2[CH:7]=1)=[O:5].[H-].[Na+].[CH2:26](Br)[CH3:27]>>[CH3:1][CH2:2][O:3][C:4]([C:6]1[N:16]([C:17]([O:19][C:20]([CH3:22])([CH3:21])[CH3:23])=[O:18])[C:9]2=[N:10][C:11]([Br:15])=[C:12]([O:14][CH2:26][CH3:27])[CH:13]=[C:8]2[CH:7]=1)=[O:5]

Participants

4

Reactant 3

HCID 6332Ethyl BromideHCID 24758Sodium hydrideHCID 73013556HCID 73013556, compound

Product 1

HCID 73013555HCID 73013555, compound

Procedure

This compound was prepared in analogy to Example 1, intermediate d) from 6-bromo-5-hydroxy-pyrrolo [2,3-b]pyridine-1,2-dicarboxylic acid 1-tert-butyl ester 2-ethyl ester, sodium hydride and ethyl bromide.

Sources & evidence

ORD record
ord-ecef38fb05254390b46bc2032b1c7637
Source dataset
uspto-grants-2007_04
Patent number
US07208494B2

Reaction notes

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