2-Propenoic acid, 3-phenyl- → Acetophenone

HRID 1276012Notes

Reaction equation

HRID 1276012 reaction equation
[O:1]=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.C([O-])(=O)[CH:14]=[CH:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[Na+].C(O)(=O)C=CC1C=CC=CC=1>>[C:15]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:1])[CH3:14]

Participants

4

Reactant 3

HCID 87842-Propenoic acid, 3-phenyl-HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 517350Sodium;3-phenylprop-2-enoate

Product 1

HCID 7410Acetophenone

Procedure

10 Liters of medium were prepared in a 14 L fermenter and were sterilized at 121° C. for 30 minutes. After sterilization, 100 g of sterile 50% dextrose solution and 100 ml of 48 hours grown inoculum were added. Periodically, after 24 hours of incubation, aliquouts of sterile 10% sodium cinnamate solution, pH 7.0 were added to maintain an approximate concentration of 5 g/L cinnamic acid.

Workup

  1. custom10 Liters of medium were prepared in a 14 L fermenter
  2. additionwere added

Sources & evidence

ORD record
ord-40267c1a8ee74e8da14c9e1bd4e99144
Source dataset
uspto-grants-2000_12
Patent number
US06165517

Reaction notes

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