Hydroxyamine hydrochloride → Hydrochloric Acid

HRID 128047Notes

Reaction equation

HRID 128047 reaction equation
[CH2:1]([C:3]1([CH2:21][CH3:22])[CH2:14][CH:13]=[CH:12][CH2:11][CH2:10][CH:9]=[CH:8][CH2:7][CH:6]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[N:5]=[CH:4]1)[CH3:2].[ClH:23].[NH2:24][OH:25]>O>[ClH:23].[CH2:1]([C:3]([CH2:21][CH3:22])([CH2:14][CH:13]=[CH:12][CH2:11][CH2:10][CH:9]=[CH:8][CH2:7][CH:6]([C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[NH2:5])[CH:4]=[N:24][OH:25])[CH3:2].[C:15]1([CH:6]([NH2:5])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:3]([CH2:21][CH3:22])([CH2:1][CH3:2])[CH2:4][NH2:24])[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

6

Reactant 2

HCID 443297Hydroxyamine hydrochlorideHCID 53954647HCID 53954647, compound

Product 3

HCID 313Hydrochloric AcidHCID 20436091HCID 20436091, compoundHCID 73678917HCID 73678917, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Reaction of 3,3-diethyl-12-phenyl-1-aza-1,5,9-cyclododecatriene with hydroxylamine hydrochloride, in the presence of hydrochloric acid and water, to 2,2-diethyl-11-phenyl-11-amino-undeca-4,8-dienal-oxime, and hydrogenation of this to yield 1-phenyl-10,10-diethyl-1,11-diaminoundecane; b.p. 146° C./2 Pa; nD20 =1.5090.

Sources & evidence

ORD record
ord-2dda302f47aa468a96db6cdd5e1e5054
Source dataset
uspto-grants-1981_03
Patent number
US04258176

Reaction notes

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