Hydrochloric Acid → HCID 20436151, compound

HRID 128049Notes

Reaction equation

HRID 128049 reaction equation
CC1(C)CC=CCCC=CCC(CCCCCC)N=C1.S(O)(O)(=O)=O.NO.Cl.[CH3:29][C:30]([CH3:50])([CH2:34][CH:35]=[CH:36][CH2:37][CH2:38][CH:39]=[CH:40][CH2:41][CH:42]([CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[NH2:43])[CH:31]=[N:32]O.C=CCCC(O)=O>O>[CH2:44]([CH:42]([NH2:43])[CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][C:30]([CH3:50])([CH3:29])[CH2:31][NH2:32])[CH2:45][CH2:46][CH2:47][CH2:48][CH3:49]

Participants

7

Reactant 5

HCID 313Hydrochloric AcidHCID 611384-Pentenoic acidHCID 159255Hydroxylamine, sulfate (1:1)HCID 54113944HCID 54113944, compoundHCID 73678918HCID 73678918, compound

Product 1

HCID 20436151HCID 20436151, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Reaction of 3,3-dimethyl-12-n-hexyl-1-aza-1,5,9-cyclododecatriene with hydroxylamine sulfate, in the presence of hydrochloric acid and water, to 2,2-dimethyl-11-n-hexyl-11-amino-undeca-4,8-dienal-oxime, and hydrogenation of this to given 1-n-hexyl-10,10-dimethyl-1,10-diaminoundecane; b.p. 135° C./4 Pa; nD20 =1.4624.

Sources & evidence

ORD record
ord-2a99b935046a4e5c8b0036b48882fd8f
Source dataset
uspto-grants-1981_03
Patent number
US04258176

Reaction notes

Loading…