Azobisisobutyronitrile → HCID 86584339, compound

HRID 1281637Notes

Reaction equation

HRID 1281637 reaction equation
[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]=[CH:2]2.[C:8]1(=[O:14])[O:13][C:11](=[O:12])[CH:10]=[CH:9]1.CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]=[CH:2]2.[C:11]1(=[O:12])[O:13][C:8](=[O:14])[CH:9]=[CH:10]1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7923Maleic AnhydrideHCID 103522-Norbornene

Product 1

HCID 86584339HCID 86584339, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
67 °C

Procedure

To 50 mL of tetrahydrofuran was added 0.2M of norbornylene, 0.2M of maleic anhydride and 0.4 g of AIBN. The resulting mixture was stirred at 67° C. for 8 hours. Thereafter, the polymer was precipitated and filtered in petroleum ether/ether(1/1) solution, to obtain poly(norbornene/maleic anhydride) of Formula 1 (yield 58%).

Workup

  1. customThereafter, the polymer was precipitated
  2. filtrationfiltered in petroleum ether/ether(1/1) solution

Sources & evidence

ORD record
ord-7e7e72a6968d44bc85ccbf947acccd52
Source dataset
uspto-grants-2002_09
Patent number
US06455226B1

Reaction notes

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