Sodium Hydroxide → 1H-Pyrrole, 3-nitro-1-(2,3,3-triiodo-2-propenyl)-

HRID 1284545Notes

Reaction equation

HRID 1284545 reaction equation
[N+:1]([C:4]1[CH:8]=[CH:7][NH:6][CH:5]=1)([O-:3])=[O:2].[I:9][C:10](=[C:23]([I:25])[I:24])[CH2:11]OS(C1C=CC(C)=CC=1)(=O)=O.[OH-].[Na+]>CN(C)C=O>[I:9][C:10](=[C:23]([I:25])[I:24])[CH2:11][N:6]1[CH:7]=[CH:8][C:4]([N+:1]([O-:3])=[O:2])=[CH:5]1

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 1458133-NitropyrroleHCID 132330032,3,3-Triiodoallyl-p-toluenesulfonate

Product 1

HCID 4970881H-Pyrrole, 3-nitro-1-(2,3,3-triiodo-2-propenyl)-

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

To a solution of 112 mg (1 mmole) of 3-nitropyrrole in 5.0 ml of dry N,N-dimethylformamide were added 606 mg of 2,3,3-triiodoallyl-p-toluenesulfonate and 60 mg (1.5 mmoles) of powdery sodium hydroxide and the reaction was carried out with stirring for 15 minutes.

Sources & evidence

ORD record
ord-2686a8e13d744e82a4f34e52502c45de
Source dataset
uspto-grants-1986_01
Patent number
US04563472

Reaction notes

Loading…