HCID 54344879, compound → HCID 53769299, compound

HRID 1287943Notes

Reaction equation

HRID 1287943 reaction equation
[C:1]1([C:7]2[CH:12]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([O:19][CH2:20][CH3:21])=[CH:15][CH:14]=3)[CH:10]=[C:9]([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=3)[N:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>C(O)(=O)C.O=[Pt]=O>[CH:22]1([C:9]2[CH:10]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([O:19][CH2:20][CH3:21])=[CH:15][CH:14]=3)[CH:12]=[C:7]([CH:1]3[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]3)[N:8]=2)[CH2:27][CH2:26][CH2:25][CH2:24][CH2:23]1

Participants

4

Reactant 1

HCID 54344879HCID 54344879, compound

Product 1

HCID 53769299HCID 53769299, compound

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 176Acetic AcidSolvent

Procedure

The 2,6 diphenyl-4-(p-ethoxyphenyl) pyridine is then dissolved in glacial acetic acid (20ml) to which 0.2g of Adam's catalyst is added. The compound is then hydrogenated at 3 atm with shaking for 4-5 hours. The catalyst and solvent were removed from the reaction mixture leaving 2,6-dicyclohexyl-4-(p-ethoxyphenyl) pyridine m.p. 106°C.

Workup

  1. additionis added
  2. customThe catalyst and solvent were removed from the reaction mixture

Sources & evidence

ORD record
ord-a0dfa531dfdb4410ab1894f482448ec3
Source dataset
uspto-grants-1976_10
Patent number
US03986140

Reaction notes

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