Diboron → HCID 53986416, compound

HRID 1288452Notes

Reaction equation

HRID 1288452 reaction equation
[I:1][C:2]1[C:10]([I:11])=[CH:9][CH:8]=[CH:7][C:3]=1[C:4](O)=[O:5].B#B>O1CCCC1>[I:1][C:2]1[C:10]([I:11])=[CH:9][CH:8]=[CH:7][C:3]=1[CH2:4][OH:5]

Participants

4

Reactant 2

HCID 6328200DiboronHCID 219647312,3-Diiodobenzoic acid

Product 1

HCID 53986416HCID 53986416, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

2,3-Diiodobenzoic acid is treated with diborane in tetrahydrofuran to give 2,3-diiodobenzyl alcohol which is oxidized to 2,3-diiodobenzaldehyde with activated manganese dioxide in methylene chloride.

Sources & evidence

ORD record
ord-6ab2ca1505a54effa09106096ae5d631
Source dataset
uspto-grants-1976_10
Patent number
US03988339

Reaction notes

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