Lithium hydroxide, monohydrate → HCID 18925569, compound

HRID 1289145Notes

Reaction equation

HRID 1289145 reaction equation
[CH3:1][C:2]12[CH2:31][CH:5]([C:6]3([CH3:30])[C:10]1([CH3:11])[C:9]1[CH:12]=[C:13]([C:16](=[O:29])[C:17]#[C:18][C:19]4[CH:28]=[CH:27][C:22]([C:23]([O:25]C)=[O:24])=[CH:21][CH:20]=4)[CH:14]=[CH:15][C:8]=1[O:7]3)[CH2:4][CH2:3]2.O.[OH-].[Li+]>O1CCCC1>[CH3:1][C:2]12[CH2:31][CH:5]([C:6]3([CH3:30])[C:10]1([CH3:11])[C:9]1[CH:12]=[C:13]([C:16](=[O:29])[C:17]#[C:18][C:19]4[CH:20]=[CH:21][C:22]([C:23]([OH:25])=[O:24])=[CH:27][CH:28]=4)[CH:14]=[CH:15][C:8]=1[O:7]3)[CH2:4][CH2:3]2

Participants

4

Reactant 2

HCID 168937Lithium hydroxide, monohydrateHCID 18925571HCID 18925571, compound

Product 1

HCID 18925569HCID 18925569, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

0.66 g of methyl ester obtained in Example 10 dissolved in 10 ml of tetrahydrofuran was treated with 200 mg of lithium hydroxide monohydrate.

Sources & evidence

ORD record
ord-f698d32e7e594289a56e86ef8a29438b
Source dataset
uspto-grants-1998_05
Patent number
US05747530

Reaction notes

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