HCID 12619394, compound → HCID 250480, compound

HRID 1354099Notes

Reaction equation

HRID 1354099 reaction equation
[CH2:1]([C:4]1([CH2:11][CH2:12][CH3:13])[CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH:2]=[CH2:3]>CO.O=[Pt]=O>[CH2:11]([C:4]1([CH2:1][CH2:2][CH3:3])[CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH2:12][CH3:13]

Participants

4

Reactant 1

HCID 12619394HCID 12619394, compound

Product 1

HCID 250480HCID 250480, compoundYield 93%

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 887MethanolSolvent

Procedure

2-Allyl-2-propylcyclohexanone (2.96 g, 16.4 mmol) and PtO2 (300 mg) were combined in MeOH (100 mL) and hydrogenated at 1 atm for 4 hrs. The catalyst was filtered off and the solvent evaporated to afford 2.78 g (93%) of 2,2-dipropylcyclohexanone as a colorless liquid. MS (CI) 183 (M+H).

Workup

  1. filtrationThe catalyst was filtered off
  2. customthe solvent evaporated

Sources & evidence

ORD record
ord-dc6c93822f5e46189e994fdab7191fa3
Source dataset
uspto-grants-2007_05
Patent number
US07223767B2

Reaction notes

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