Benzyl mercaptan → HCID 18507489, compound

HRID 1355891Notes

Reaction equation

HRID 1355891 reaction equation
[Br:1][C:2]1[C:3]([C:12]2[O:13][CH:14]=[CH:15][CH:16]=2)=[N:4][C:5]([NH2:11])=[N:6][C:7]=1[S:8]([CH3:10])=O.C(S)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.C1CCN2C(=NCCC2)CC1>O1CCOCC1>[CH2:10]([S:8][C:7]1[C:2]([Br:1])=[C:3]([C:12]2[O:13][CH:14]=[CH:15][CH:16]=2)[N:4]=[C:5]([NH2:11])[N:6]=1)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

5

Reactant 3

HCID 7509Benzyl mercaptanHCID 811841,8-Diazabicyclo(5.4.0)undec-7-eneHCID 185072865-Bromo-4-furan-2-yl-6-methanesulfinyl-pyrimidin-2-ylamine

Product 1

HCID 18507489HCID 18507489, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

From 5-bromo-4-furan-2-yl-6-methanesulfinyl-pyrimidin-2-yl-amine, benzylmercaptan and DBU in dioxane. EI-MS m/e (%): 363 (M{81Br}+, 48), 361 (M{79Br}+, 46), 282 ([M—Br]+, 68), 249 (35), 91 (100).

Sources & evidence

ORD record
ord-d7e40acadddd4b44a3465bb9a2ef0ad0
Source dataset
uspto-grants-2003_07
Patent number
US06586441B2

Reaction notes

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