Sodium ion → Methyl 3-methyl-4-oxooxane-3-carboxylate

HRID 135924Notes

Reaction equation

HRID 135924 reaction equation
[CH3:32][CH2:33][O:34][C:35](=[O:36])[CH3:37].[H-:23].[I:25][CH3:26].[Na+:24].[O:1]=[C:2]1[CH:3]([C:8](=[O:9])[O:10][CH3:11])[CH2:4][O:5][CH2:6][CH2:7]1.[O:27]=[CH:28][N:29]([CH3:30])[CH3:31].[OH:12][C:13]1=[C:18]([C:19]([O:20][CH3:21])=[O:22])[CH2:17][O:16][CH2:15][CH2:14]1>>[O:1]=[C:2]1[C:3]([C:8](=[O:9])[O:10][CH3:11])([CH3:13])[CH2:4][O:5][CH2:6][CH2:7]1

Participants

8

Reactant 7

HCID 923Sodium ionHCID 6228DimethylformamideHCID 6328Methyl iodideHCID 8857Ethyl AcetateHCID 166653HydrideHCID 14666555Methyl 4-oxooxane-3-carboxylateHCID 68541653methyl 4-hydroxy-5,6-dihydro-2H-pyran-3-carboxylate

Product 1

HCID 68819284Methyl 3-methyl-4-oxooxane-3-carboxylate

Sources & evidence

ORD record
ord-177016121289483a943c0b41cf80783b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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