Phenol → HCID 86584687, compound

HRID 1369906Notes

Reaction equation

HRID 1369906 reaction equation
[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][Al:9](C)C>CCCCCC>[O-:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][Al+2:9]

Participants

4

Reactant 2

HCID 996PhenolHCID 16682925Trimethylaluminum

Product 1

HCID 86584687HCID 86584687, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent2×

Procedure

Under an argon atomosphere, 5 g of phenol was dissolved in 25 ml of hexane. This was added dropwise to 26.5 ml of a hexane solution containing 1.0 M trimethylaluminum at −20° C. over 1 hour. This was brought to room temperature and allowed to stand overnight. The precipitate was filtered and washed with hexane. Recrystallization from ether gave 4.36 g of methylaluminum diphenoxide.

Workup

  1. customThis was brought to room temperature
  2. filtrationThe precipitate was filtered
  3. washwashed with hexane
  4. customRecrystallization from ether

Sources & evidence

ORD record
ord-44923f6f0eb740fa8e6647bda6349b63
Source dataset
uspto-grants-2003_06
Patent number
US06579956B2

Reaction notes

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