Toluene → HCID 21079864, compound

HRID 1375219Notes

Reaction equation

HRID 1375219 reaction equation
C1(C)C=CC=CC=1.ClC1C(=O)C(C#N)=C(C#N)C(=O)C=1Cl.[F:22][S:23]([CH:28]1[C:37]2[C:32](=[CH:33][CH:34]=[CH:35][CH:36]=2)[CH2:31][CH:30]=[CH:29]1)([F:27])([F:26])([F:25])[F:24]>CCCCC>[F:22][S:23]([C:28]1[C:37]2[C:32](=[CH:33][CH:34]=[CH:35][CH:36]=2)[CH:31]=[CH:30][CH:29]=1)([F:27])([F:26])([F:25])[F:24]

Participants

5

Reactant 3

HCID 1140TolueneHCID 67752,3-Dichloro-5,6-dicyano-1,4-benzoquinoneHCID 21079866HCID 21079866, compound

Product 1

HCID 21079864HCID 21079864, compound

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Conditions

Temperature
65 °C

Procedure

Toluene and dichlorodicyanobenzoquinone (2 equivalents) were added to the product of step 2 and heated to 65° C. The reaction was monitored by GC. When the reaction was complete pentane was added. Resulting solids were removed by filtration. Color was removed by filtering through silica. The crude product was isolated by removing the solvent using rotary evaporation.

Workup

  1. additionwas added
  2. customResulting solids
  3. customwere removed by filtration
  4. customColor was removed
  5. filtrationby filtering through silica

Sources & evidence

ORD record
ord-8ce6d48b03bc43dfb989b909d22d32cf
Source dataset
uspto-grants-2007_01
Patent number
US07166755B2

Reaction notes

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