Diisopropyl Ether → HCID 15616471, compound

HRID 1377385Notes

Reaction equation

HRID 1377385 reaction equation
[C:1]([O:6][CH2:7][CH2:8][N:9]([CH3:11])[CH3:10])(=[O:5])[C:2]([CH3:4])=[CH2:3].C(OC(C)C)(C)C.COC1C=CC(O)=CC=1.[Br:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]>>[Br-:28].[C:1]([O:6][CH2:7][CH2:8][N+:9]([CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH3:29])([CH3:11])[CH3:10])(=[O:5])[C:2]([CH3:4])=[CH2:3]

Participants

5

Reactant 4

HCID 7914Diisopropyl EtherHCID 89191-BromododecaneHCID 90154-MethoxyphenolHCID 17869(Dimethylamino)ethyl methacrylate

Product 1

HCID 15616471HCID 15616471, compound

Procedure

Into a two-necked flask provided with a reflux condenser and a dropping funnel were introduced 94.3 g (0.6 mol) of methacryloyloxyethyl-N,N-dimethylamine, 78 g of isopropyl ether and 0.1 g of hydroquinone monomethyl ether, which was employed as a polymerization inhibitor, and mixed homogeneously. After dropping 149.5 g (0.6 mol) of 1-bromododecane thereinto within about 15 minutes, the mixture was allowed to stand overnight under stirring at room temperature. Then the reaction mixture was washed with 500 ml of isopropyl ether to obtain crystals of methacryloyloxyethyl-N,N-dimethyldodecylammonium bromide.

Workup

  1. customInto a two-necked flask provided with a reflux condenser and a dropping funnel
  2. additionmixed homogeneously
  3. waitto stand overnight
  4. washThen the reaction mixture was washed with 500 ml of isopropyl ether

Sources & evidence

ORD record
ord-d1aeddd068ba4015ae3fcbcee096a65f
Source dataset
uspto-grants-1997_09
Patent number
US05665348

Reaction notes

Loading…