HRID137930

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1140

Toluene

C7H8

HCID11776

Triphenylphosphine

C18H15P

4 次

HCID23938

Palladium

结构：C=[CH][Sn]([CH2]CCC)([CH2]CCC)[CH2]CCC

HCID81998

Ethynyltributylstannane

C14H30Sn

HCID18379725

5-Bromo-6-fluoropyridin-3-amine

C5H4BrFN2

PRODUCTS

生成物

HCID18458935

5-Ethenyl-6-fluoropyridin-3-amine

C7H7FN2

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9ed944222b484064b35dfbf10cd95c63
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[CH2:10]([CH2:11][CH2:23][CH3:24])[Sn:12]([CH2:13][CH2:14][CH2:15][CH3:16])([CH2:17][CH2:18][CH2:19][CH3:20])[CH:21]=[CH2:22].[CH3:25][c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1.[NH2:1][c:2]1[cH:3][c:4]([Br:9])[c:5]([F:8])[n:6][cH:7]1.[Pd:32].[c:33]1([P:34]([c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[c:41]2[cH:42][cH:43][cH:44][cH:45][cH:46]2)[cH:47][cH:48][cH:49][cH:50][cH:51]1.[c:52]1([P:53]([c:54]2[cH:55][cH:56][cH:57][cH:58][cH:59]2)[c:60]2[cH:61][cH:62][cH:63][cH:64][cH:65]2)[cH:66][cH:67][cH:68][cH:69][cH:70]1.[c:71]1([P:72]([c:73]2[cH:74][cH:75][cH:76][cH:77][cH:78]2)[c:79]2[cH:80][cH:81][cH:82][cH:83][cH:84]2)[cH:85][cH:86][cH:87][cH:88][cH:89]1.[c:90]1([P:91]([c:92]2[cH:93][cH:94][cH:95][cH:96][cH:97]2)[c:98]2[cH:99][cH:100][cH:101][cH:102][cH:103]2)[cH:104][cH:105][cH:106][cH:107][cH:108]1>>[NH2:1][c:2]1[cH:3][c:4]([CH:10]=[CH2:11])[c:5]([F:8])[n:6][cH:7]1