HRID1380710

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8471

Triethylamine

C6H15N

HCID61330

Dichlorosilane

H2Cl2Si

结构：CC(C)(C)c1cc(Cc2cc(C(C)(C)C)cc(C(C)(C)C)c2O)c(O)c(C(C)(C)C)c1

HCID84391

2,2′-Methylenebis[4,6-bis(1,1-dimethylethyl)phenol]

C29H44O2

HCID18522661

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)c1cc2c(c(C(C)(C)C)c1)O[SiH2]Oc1c(cc(C(C)(C)C)cc1C(C)(C)C)C2

HCID102330274

未命名化合物

收率 57.2%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

In a flame-dried flask equipped with a dry ice-acetone filled Dewar condenser and a sintered glass inlet, 42.5 grams (0.1 mole) 2,2'-methylene-bis(4,6-di-t-butylphenol) and 20.2 grams (0.2 mole) triethylamine dissolved in 100 ml tetrahydrofuran are treated slowly with 11.1 grams (0.11 mole) dichlorosilane. Filtration and recrystallization from acetonitrile-toluene gave 25.9 grams (57% yield) of a white solid mp 189°-192° C. The 1H NMR spectrum is consistent with the product.

WORKUP

后处理

filtrationFiltration and recrystallization from acetonitrile-toluene