Benzoic Acid → HCID 131714642, compound

HRID 1381033Notes

Reaction equation

HRID 1381033 reaction equation
[CH:1]([CH2:3][SiH:4](Cl)Cl)=[CH2:2].[C:7]([OH:15])(=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>CCCCCC>[CH:1]([CH2:3][SiH:4]([O:15][C:7](=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[O:14][C:7](=[O:15])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[CH2:2]

Participants

4

Reactant 2

HCID 243Benzoic AcidHCID 77536Dichloro(prop-2-enyl)silane

Product 1

HCID 131714642HCID 131714642, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

705 g (5 moles) of vinylmethyldichlorosilane and 1000 ml of hexane are placed in the apparatus of Example 1. The reaction with 1245 g of benzoic acid (=10.2 moles) is performed as described under Example 1; the distillation of the raw product is performed in the same manner. At a pressure of 0.5 mbar and a head temperature of 141° C., 1295 g (4.15 moles) of a colorless liquid is distilled off. The yield amounts to 83%.

Workup

  1. distillationthe distillation of the raw product

Sources & evidence

ORD record
ord-f8bae57dc271466ab90908109767a157
Source dataset
uspto-grants-1986_04
Patent number
US04584394

Reaction notes

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