Benzoic Acid → HCID 23325081, compound

HRID 1381034Notes

Reaction equation

HRID 1381034 reaction equation
[CH2:1]([Si:4](Cl)(Cl)Cl)[CH:2]=[CH2:3].[C:8]([OH:16])(=[O:15])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>CCCCCC>[CH2:1]([Si:4]([O:16][C:8](=[O:15])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)([O:15][C:8](=[O:16])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[O:15][C:8](=[O:16])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 243Benzoic AcidHCID 7867Trichloro-2-propen-1-ylsilane

Product 1

HCID 23325081HCID 23325081, compoundYield 74%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

878 g (5 moles) of allyltrichlorosilane and 1000 ml of hexane are placed in the apparatus of Example 1. The reaction with 1855 g of benzoic acid (=15.2 mol) is performed as described in Example 1, as is also the distilling of the raw product. At a pressure of 0.4 mbar and a head temperature of 137° C., 1599 g (3.7 mol) of a colorless liquid is distilled out, which several days later transforms to a sticky-crystalline state. The yield of 74%.

Workup

  1. distillationdistilling of the raw product
  2. customwhich several days

Sources & evidence

ORD record
ord-2d7ac2f78a7a46848691fc0da5d6e946
Source dataset
uspto-grants-1986_04
Patent number
US04584394

Reaction notes

Loading…