HRID1383028

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5395

1,4-Dihydroxy-2,2,6,6-tetramethylpiperidine

C9H19NO2

HCID24387

Phosphorous trichloride

Cl3P

结构：CC(c1cc(C(C)(C)C)cc(C(C)(C)C)c1O)c1cc(C(C)(C)C)cc(C(C)(C)C)c1O

HCID118899

Tetrabutyl ethylidenebisphenol

C30H46O2

PRODUCTS

生成物

结构：CC1c2cc(C(C)(C)C)cc(C(C)(C)C)c2OP(OC2CC(C)(C)N(O)C(C)(C)C2)Oc2c1cc(C(C)(C)C)cc2C(C)(C)C

HCID21273724

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

The above-named compound is prepared using the general procedure of Example 1 by reacting 4.4 ml of phosphorous trichloride, 21.94 grams of 2,2'-ethylidenebis(4,6-di-tert-butylphenol), 19.3 ml of triethylamine and 6.68 grams of 1,4-dihydroxy-2,2,6,6-tetramethylpiperidine.

WORKUP

后处理

customThe above-named compound is prepared

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5c7974e745bf422b839defa12bd80747
来源数据集: uspto-grants-1989_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04808645
来源说明: uspto-grants-1989_02

反应 SMILES

[P:1](Cl)(Cl)Cl.[CH:5]([C:22]1[CH:27]=[C:26]([C:28]([CH3:31])([CH3:30])[CH3:29])[CH:25]=[C:24]([C:32]([CH3:35])([CH3:34])[CH3:33])[C:23]=1[OH:36])([C:7]1[CH:12]=[C:11]([C:13]([CH3:16])([CH3:15])[CH3:14])[CH:10]=[C:9]([C:17]([CH3:20])([CH3:19])[CH3:18])[C:8]=1[OH:21])[CH3:6].[OH:37][N:38]1[C:43]([CH3:45])([CH3:44])[CH2:42][CH:41]([OH:46])[CH2:40][C:39]1([CH3:48])[CH3:47]>C(N(CC)CC)C>[C:28]([C:26]1[CH:25]=[C:24]([C:32]([CH3:35])([CH3:34])[CH3:33])[C:23]2[O:36][P:1]([O:46][CH:41]3[CH2:42][C:43]([CH3:44])([CH3:45])[N:38]([OH:37])[C:39]([CH3:48])([CH3:47])[CH2:40]3)[O:21][C:8]3[C:9]([C:17]([CH3:20])([CH3:18])[CH3:19])=[CH:10][C:11]([C:13]([CH3:16])([CH3:14])[CH3:15])=[CH:12][C:7]=3[CH:5]([CH3:6])[C:22]=2[CH:27]=1)([CH3:31])([CH3:30])[CH3:29]