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HRID1383362

反应详情

EQUATION

反应方程式

HRID 1383362 的结构方程式

REACTANTS

反应物

2
结构：Cc1cc(C)cc(Cl)c1
HCID32887

Benzene, 1-chloro-3,5-dimethyl- (9CI)

C8H9Cl

结构：O=C1CCC(=O)N1Br
HCID67184

1-Bromopyrrolidine-2,5-dione

C4H4BrNO2

PRODUCTS

生成物

1
结构：Cc1cc(Cl)cc(CBr)c1
HCID12375549

未命名化合物

收率 81.5%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC(C)(C#N)N=NC(C)(C)C#N
催化剂HCID6547

Azobisisobutyronitrile

C8H12N4

结构：ClC(Cl)(Cl)Cl
溶剂HCID5943

Carbon tetrachloride

CCl4

PROCEDURE

实验过程

A solution of 5-chloro-m-xylene (14.06 g; 0.1 mol), NBS (17.8 g; 0.1 mol) and AIBN (1.1 g; 6.7 mmol) in CCl4 was refluxed for two hours. The resultant mixture was cooled, and the solid material formed was removed by filtration. Concentration yielded the sub-title compound (17.9 g; 80%).

WORKUP

后处理

  1. customthe solid material formed
  2. customwas removed by filtration
  3. concentrationConcentration