Tert-Butylamine → HCID 54409688, compound

HRID 1384439Notes

Reaction equation

HRID 1384439 reaction equation
[CH2:1]1[C:5]2[CH:6]=[CH:7][C:8]3[C:17]([C:4]=2[CH:3]=[C:2]1[Si:18]([CH3:21])([CH3:20])Cl)=[CH:16][CH:15]=[C:14]1[C:9]=3[CH:10]=[CH:11][CH:12]=[CH:13]1.[C:22]([NH2:26])([CH3:25])([CH3:24])[CH3:23]>CCCCCC>[CH2:1]1[C:5]2[CH:6]=[CH:7][C:8]3[C:17]([C:4]=2[CH:3]=[C:2]1[Si:18]([CH3:21])([CH3:20])[NH:26][C:22]([CH3:25])([CH3:24])[CH3:23])=[CH:16][CH:15]=[C:14]1[C:9]=3[CH:10]=[CH:11][CH:12]=[CH:13]1

Participants

4

Reactant 2

HCID 6385Tert-ButylamineHCID 57000024HCID 57000024, compound

Product 1

HCID 54409688HCID 54409688, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

To a 500 ml round bottom flask containing 1.98 g (0.0064 mole) of (1H-cyclopenta[I] phenanthrene-2-yl) dimethylchlorosilane and 250 ml of hexane was added 2.00 ml (0.0160 mole) of t-butylamine. The reaction mixture was allowed to stir for several days, then filtered using diatomaceous earth filter aid (CeliteTM), washed twice with hexane. The product was isolated by removing residual solvent under reduced pressure. The isolated yield was 1.98 g (88.9 percent).

Workup

  1. filtrationfiltered
  2. filtrationfilter aid (CeliteTM)
  3. washwashed twice with hexane
  4. customThe product was isolated
  5. customby removing residual solvent under reduced pressure

Sources & evidence

ORD record
ord-3bcca1ec67d944f3ad6b5c64a29a8873
Source dataset
uspto-grants-2001_07
Patent number
US06258902B1

Reaction notes

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