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HRID1386457

反应详情

EQUATION

反应方程式

HRID 1386457 的结构方程式

REACTANTS

反应物

4
反应SMILES：OCCO
HCID174

Ethylene glycol

C2H6O2

反应SMILES：O
HCID962

Water

H2O

反应SMILES：Cc1ccc(S(=O)(=O)O)cc1
HCID6101

4-Methylbenzenesulfonic acid

C7H8O3S

反应SMILES：COCCCCC(C)(C)C(=O)CP(=O)(OC)OC
HCID15223961

Dimethyl (7-methoxy-3,3-dimethyl-2-oxoheptyl)phosphonate

C12H25O5P

PRODUCTS

产物

1
反应SMILES：CCCCC(OC1CCCCO1)C(=O)CP(=O)(OC)OC
HCID54345769

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
反应SMILES：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

The ketone (4) (1.95 g) was dissolved in toluene (150 ml), and ethylene glycol and p-toluenesulfonic acid (catalytic amount) were added. The solution was heated under reflux overnight while water produced was distilled off. After the usual work-up, ketal (5) was obtained. Yield: 1.8 g (84%).

WORKUP

后处理

  1. temperatureThe solution was heated
  2. customproduced
  3. distillationwas distilled off