HRID13866

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID28118

Fluoboric acid

HBF4

HCID75806

Phosphine, tricyclohexyl-

C18H33P

结构：[Na+].c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID2723787

Borate(1-), tetraphenyl-, sodium

C24H20BNa

结构：C1CCC([PH+](C2CCCCC2)C2CCCCC2)CC1.F[B-](F)(F)F

HCID11710396

TRICYCLOHEXYLPHOSPHONIUM TETRAFLUOROBORATE

C18H34BF4P

PRODUCTS

生成物

结构：C1CCC([PH+](C2CCCCC2)C2CCCCC2)CC1.c1ccc([B-](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID23136635

未命名化合物

收率 75%

PROCEDURE

实验过程

Tricyclohexylphosphine is reacted with fluoroboric acid to synthesize tricyclohexylphosphonium tetrafluoroborate, which is reacted with sodium tetraphenylborate to produce tricyclohexylphosphonium tetraphenylborate (75% yield). A similar process is described in which tri-tert-butylphosphine is used as starting material to produce tri-tert-butylphosphonium tetraphenylborate (71% yield) (see Nonpatent Document 4).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-26bcb57d0e5a476a8aaa17b3207a4354
来源数据集: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07728176B2
来源说明: uspto-grants-2010_06

反应 SMILES

[CH:1]1([P:7]([CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.F[B-](F)(F)F.[H+].F[B-](F)(F)F.C1([PH+](C2CCCCC2)C2CCCCC2)CCCCC1.[C:50]1([B-:56]([C:69]2[CH:74]=[CH:73][CH:72]=[CH:71][CH:70]=2)([C:63]2[CH:68]=[CH:67][CH:66]=[CH:65][CH:64]=2)[C:57]2[CH:62]=[CH:61][CH:60]=[CH:59][CH:58]=2)[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1.[Na+]>>[C:69]1([B-:56]([C:50]2[CH:51]=[CH:52][CH:53]=[CH:54][CH:55]=2)([C:57]2[CH:58]=[CH:59][CH:60]=[CH:61][CH:62]=2)[C:63]2[CH:68]=[CH:67][CH:66]=[CH:65][CH:64]=2)[CH:70]=[CH:71][CH:72]=[CH:73][CH:74]=1.[CH:14]1([PH+:7]([CH:1]2[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1