m-Chloroperbenzoic acid → HCID 54435346, compound

HRID 1388135Notes

Reaction equation

HRID 1388135 reaction equation
[CH2:1]([O:3][C:4](=[O:20])[C:5](=[CH2:19])[CH2:6][CH2:7][CH2:8][CH2:9][O:10][CH2:11][CH2:12][CH:13]1[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1)[CH3:2].ClC1C=CC=C(C(OO)=[O:29])C=1>C(Cl)Cl>[CH2:1]([O:3][C:4]([C:5]1([CH2:6][CH2:7][CH2:8][CH2:9][O:10][CH2:11][CH2:12][CH:13]2[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]2)[CH2:19][O:29]1)=[O:20])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 53689540HCID 53689540, compound

Product 1

HCID 54435346HCID 54435346, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

5.3 g of the title compound, in the form of an oil, which is purified by chromatography on silica gel (migrating agent: 9:1 petroleum ether/ethyl acetate), are obtained by the procedure described in Example (1a) from 11.2 g of 6-(2-cyclohexylethoxy)-2-methylenehexanoic acid ethyl ester and 13.7 g of m-chloroperbenzoic acid in 100 ml of methylene chloride.

Workup

  1. custom5.3 g of the title compound, in the form of an oil, which is purified by chromatography on silica gel (migrating agent: 9:1 petroleum ether/ethyl acetate)
  2. customare obtained by the procedure

Sources & evidence

ORD record
ord-40484e3933ae4caa8634a9057cc31751
Source dataset
uspto-grants-1984_02
Patent number
US04430339

Reaction notes

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