m-Chloroperbenzoic acid → HCID 53977619, compound

HRID 1388143Notes

Reaction equation

HRID 1388143 reaction equation
[CH2:1]([O:3][C:4](=[O:18])[C:5](=[CH2:17])[CH2:6][CH2:7][CH2:8][CH:9]1[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]1)[CH3:2].ClC1C=CC=C(C(OO)=[O:27])C=1>C(Cl)Cl>[CH2:1]([O:3][C:4]([C:5]1([CH2:6][CH2:7][CH2:8][CH:9]2[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]2)[CH2:17][O:27]1)=[O:18])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 53902482HCID 53902482, compound

Product 1

HCID 53977619HCID 53977619, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.2 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate), are obtained by the procedure described in Example (1a) from 5.42 g of 5-cyclooctyl-2-methylenevaleric acid ethyl ester and 5.55 g of m-chloroperbenzoic acid in 50 ml of methylene chloride.

Workup

  1. custom2.2 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate)
  2. customare obtained by the procedure

Sources & evidence

ORD record
ord-054a474f45664e3186ec176535120c6c
Source dataset
uspto-grants-1984_02
Patent number
US04430339

Reaction notes

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