m-Chloroperbenzoic acid → HCID 53815920, compound

HRID 1388145Notes

Reaction equation

HRID 1388145 reaction equation
[CH2:1]([O:3][C:4](=[O:21])[C:5](=[CH2:20])[CH2:6][CH2:7][CH2:8][CH:9]1[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]1)[CH3:2].ClC1C=CC=C(C(OO)=[O:30])C=1>C(Cl)Cl>[CH2:1]([O:3][C:4]([C:5]1([CH2:6][CH2:7][CH2:8][CH:9]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]2)[CH2:20][O:30]1)=[O:21])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 53780670HCID 53780670, compound

Product 1

HCID 53815920HCID 53815920, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.2 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate; thin layer chromatography on silica gel with petroleum ether/ethyl acetate 9:1:Rf =0.5), are obtained by the procedure described in Example (1a) from 4.4 g of 5-cycloundecyl-2-methylenevaleric acid ethyl ester and 5.15 g of m-chloroperbenzoic acid in 40 ml of methylene chloride.

Workup

  1. custom2.2 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate; thin layer chromatography on silica gel with petroleum ether/ethyl acetate 9:1:Rf =0.5)
  2. customare obtained by the procedure

Sources & evidence

ORD record
ord-be5bfb00b0704340ad971811f0e3d179
Source dataset
uspto-grants-1984_02
Patent number
US04430339

Reaction notes

Loading…