m-Chloroperbenzoic acid → HCID 53848094, compound

HRID 1388154Notes

Reaction equation

HRID 1388154 reaction equation
[CH2:1]([O:3][C:4](=[O:19])[C:5](=[CH2:18])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]1[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]1)[CH3:2].ClC1C=CC=C(C(OO)=[O:28])C=1>C(Cl)Cl>[CH2:1]([O:3][C:4]([C:5]1([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]2[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17]2)[CH2:18][O:28]1)=[O:19])[CH3:2]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54022117HCID 54022117, compound

Product 1

HCID 53848094HCID 53848094, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

7.5 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate; thin layer chromatography on silica gel with petroleum ether/ethyl acetate 8:2: Rf =0.55), are obtained by the procedure described in Example (1a) from 13.1 g of 7-cycloheptyl-2-methyleneheptanoic acid ethyl ester and 12.0 g of m-chloroperbenzoic acid in 200 ml of methylene chloride.

Workup

  1. custom7.5 g of the title compound, in the form of a colourless oil, which is purified by chromatography on silica gel (migrating agent: 90:10 petroleum ether/ethyl acetate; thin layer chromatography on silica gel with petroleum ether/ethyl acetate 8:2: Rf =0.55)
  2. customare obtained by the procedure

Sources & evidence

ORD record
ord-b815dcde26b84132afb93224344fb9a9
Source dataset
uspto-grants-1984_02
Patent number
US04430339

Reaction notes

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