Hydrochloric Acid → HCID 73177919, compound

HRID 1390861Notes

Reaction equation

HRID 1390861 reaction equation
[CH3:1][O:2][C:3]([O:12][CH3:13])([CH2:9][CH2:10][CH3:11])[C:4](=[N:7][OH:8])[CH2:5][CH3:6].[ClH:14].ClCl>C(Cl)Cl>[Cl:14][CH:9]([CH2:10][CH3:11])[C:3]([O:2][CH3:1])([O:12][CH3:13])[C:4](=[N:7][OH:8])[CH2:5][CH3:6]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 24526ChlorineHCID 73177918HCID 73177918, compound

Product 1

HCID 73177919HCID 73177919, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Following the general procedure of Example 1, to a solution of 4.73 parts of 4,4-dimethoxy-3-oximinoheptane and 0.2 parts anhydrous hydrogen chloride dissolved in 20 parts dry methylene chloride, at 30 to 35° C., under a dry nitrogen atmosphere, was added 1.8 parts of elemental chlorine over a 1/2-hour period. After the addition, the contents were stirred for 1/2-hour and then treated according to the procedure in Example 1 to yield 3.5 parts of 5-chloro-4,4-dimethoxy-3-oximinoheptane as determined by nuclear magnetic resonance spectroscopy.

Workup

  1. additionAfter the addition
  2. additiontreated

Sources & evidence

ORD record
ord-4fbc04e6d50e4d89884998bd496b99b0
Source dataset
uspto-grants-1979_02
Patent number
US04140717

Reaction notes

Loading…