Methylamine → HCID 12901514, compound

HRID 1391055Notes

Reaction equation

HRID 1391055 reaction equation
[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([N+:11]([O-:13])=[O:12])[C:6]=1[N+:14]([O-])=O)[CH:2]=[CH2:3].[CH3:17]N>C(O)(C)C>[CH2:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([N+:11]([O-:13])=[O:12])[C:6]=1[NH:14][CH3:17])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 6329MethylamineHCID 20555071HCID 20555071, compound

Product 1

HCID 12901514HCID 12901514, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

A mixture of 9.0 g of 1-allyloxy-2,3-dinitrobenzene, 400 ml of isopropanol and 12.4 g of gaseous methylamine is heated, in a pressure vessel, to 90° for 3 hours, whilst stirring. After cooling and letting-down, the reaction solution is evaporated under reduced pressure. The resulting oil is dried at 50°/0.01 mm Hg for 2 hours, whereupon 1-allyloxy-2-methylamino-3-nitrobenzene is obtained; this can be used further without purification.

Workup

  1. temperatureis heated, in a pressure vessel, to 90° for 3 hours
  2. temperatureAfter cooling
  3. customthe reaction solution is evaporated under reduced pressure
  4. customThe resulting oil is dried at 50°/0.01 mm Hg for 2 hours

Sources & evidence

ORD record
ord-507f4618e71241ba975fb5f8ae511b38
Source dataset
uspto-grants-1979_02
Patent number
US04140789

Reaction notes

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