HRID1391108

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID757

Glycolic acid

C2H4O3

HCID887

Methanol

CH4O

HCID21332347

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCC(O)CNCCCCCCNCC(O)CCCCCCCCC.O=C(O)COCC(=O)O

HCID86734722

未命名化合物

PROCEDURE

实验过程

A solution of N,N'-(1,6-hexylene-bis[2-hydroxyundecylamine] (5 g.), glycolic acid (1.66 g.) and methanol was heated until the solids dissolved, then evaporated to dryness. Recrystallization of the solid from acetone afforded N,N'-(1,6-hexylene)bis[2-hydroxyundecylamine] diglycolate (4.6 g., m.p. 88.2°-94.6° C.).

WORKUP

后处理

dissolutiondissolved
customevaporated to dryness
customRecrystallization of the solid from acetone

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-acf8e565aedb4f45ba87308302744d0a
来源数据集: uspto-grants-1979_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04140860
来源说明: uspto-grants-1979_02

反应 SMILES

[CH2:1]([NH:20][CH2:21][CH:22]([OH:32])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][NH:7][CH2:8][CH:9]([OH:19])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[C:33]([OH:37])(=[O:36])[CH2:34][OH:35].C[OH:39]>>[C:33]([OH:37])(=[O:36])[CH2:34][O:35][CH2:23][C:22]([OH:32])=[O:39].[CH2:1]([NH:20][CH2:21][CH:22]([OH:32])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][NH:7][CH2:8][CH:9]([OH:19])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]