Ethyl diazoacetate → HCID 12389515, compound

HRID 1395184Notes

Reaction equation

HRID 1395184 reaction equation
[N+](=[CH:3][C:4]([O:6][CH2:7][CH3:8])=[O:5])=[N-].[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>S([O-])([O-])(=O)=O.[Cu+2]>[CH2:11]([CH:10]1[CH2:9][CH:3]1[C:4]([O:6][CH2:7][CH3:8])=[O:5])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

4

Reactant 2

HCID 12192Ethyl diazoacetateHCID 133811-Decene2×

Product 1

HCID 12389515HCID 12389515, compound

Reagents, catalysts & solvents 1

HCID 24462Copper SulfateCatalyst

Procedure

A mixture of 60 g of ethyl diazoacetate and 100 g of decene was added drop-by-drop to a stirred suspension of 4 g of anhydrous copper sulfate in 700 g of decene, at 105° C. The addition required 1.5 hours. The mixture was stirred for an additional 2 hours, then filtered, and the filtrate was distilled, to give 1, as a liquid, bp: 107°-110° C. (0.1 Torr.).

Workup

  1. additionThe addition required 1.5 hours
  2. filtrationfiltered
  3. distillationthe filtrate was distilled
  4. customto give 1

Sources & evidence

ORD record
ord-add164aa861d4d2683793d2cb1a128ce
Source dataset
uspto-grants-1980_05
Patent number
US04202902

Reaction notes

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