Allylamine → HCID 20337912, compound

HRID 1395681Notes

Reaction equation

HRID 1395681 reaction equation
[C:1]1([C:7]2[CH:8]=[CH:9][C:10]3[O:14][CH:13]([C:15]([O:17]CC)=O)[CH2:12][C:11]=3[CH:20]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:21]([NH2:24])[CH:22]=[CH2:23]>C(O)C>[C:1]1([C:7]2[CH:8]=[CH:9][C:10]3[O:14][CH:13]([C:15]([NH:24][CH2:21][CH:22]=[CH2:23])=[O:17])[CH2:12][C:11]=3[CH:20]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 7853AllylamineHCID 20337911HCID 20337911, compound

Product 1

HCID 20337912HCID 20337912, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

An ethanol solution of 1E and an excess of 2-propenamine was refluxed for 2.5 days. The excess amine and the solvent were evaporated under reduced pressure. The resulting gum was recrystallized from methylene chloride/hexane to give 1, as a white solid, mp: 112° C.

Workup

  1. customThe excess amine and the solvent were evaporated under reduced pressure
  2. customThe resulting gum was recrystallized from methylene chloride/hexane
  3. customto give 1

Sources & evidence

ORD record
ord-1d615ecc0105419eb323e41545e349d2
Source dataset
uspto-grants-1980_05
Patent number
US04205080

Reaction notes

Loading…