Pyrrole → HCID 86673204, compound

HRID 1400786Notes

Reaction equation

HRID 1400786 reaction equation
[CH:1]1[C:14]2[C:15]3=[C:16]4[C:11](=[CH:12][CH:13]=2)[CH:10]=[CH:9][CH:8]=[C:7]4[CH:6]=[CH:5][C:4]3=[CH:3][CH:2]=1.[NH:17]1[CH:21]=[CH:20][CH:19]=[CH:18]1>[N+](C)([O-])=O>[CH:8]1[C:7]2[C:16]3=[C:15]4[C:4](=[CH:5][CH:6]=2)[CH:3]=[CH:2][CH:1]=[C:14]4[CH:13]=[CH:12][C:11]3=[CH:10][CH:9]=1.[NH:17]1[CH:21]=[CH:20][CH:19]=[CH:18]1

Participants

4

Reactant 2

HCID 8027Pyrrole2×HCID 31423Pyrene2×

Product 1

HCID 86673204HCID 86673204, compound

Reagents, catalysts & solvents 1

HCID 6375NitromethaneSolvent

Procedure

To investigate the initiation and progression of the copolymerization reaction, the open circuit potential and the polymerization temperature of the reaction mixture are monitored during the copolymerization. Pyrene and pyrrole are reacted at different molar ratios using anhydrous ferric chloride as the oxidant in the presence of nitromethane. The molar ratios of pyrene to pyrrole (Pyre/Pyrr) added to the reaction are 90:10, 70:30, and 30:70, respectively. The molar ratio of oxidant to the total amount of the monomers for each reaction is 5:1. The reaction is conducted at 50° C. for 30 hours.

Workup

  1. customthe initiation and progression of the copolymerization reaction
  2. customthe open circuit potential and the polymerization temperature of the reaction mixture are monitored during the copolymerization

Sources & evidence

ORD record
ord-cde47d007d974831afff6d253baa9bc6
Source dataset
uspto-grants-2014_12
Patent number
US08907015B2

Reaction notes

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