Triethylamine → 4,4-Dimethyl-7-((trimethylsilyl)ethynyl)-3,4-dihydronaphthalen-1(2H)-one

HRID 140976Notes

Reaction equation

HRID 140976 reaction equation
[CH3:16][Si:17]([CH3:18])([CH3:19])[C:20]#[CH:21].[CH3:1][C:2]1([CH3:14])[CH2:3][CH2:4][C:5](=[O:13])[c:6]2[cH:7][c:8]([Br:12])[cH:9][cH:10][c:11]21.[CH3:22][CH2:23][N:24]([CH2:25][CH3:26])[CH2:27][CH3:28].[I-:15]>>[CH3:1][C:2]1([CH3:14])[CH2:3][CH2:4][C:5](=[O:13])[c:6]2[cH:7][c:8]([C:21]#[C:20][Si:17]([CH3:16])([CH3:18])[CH3:19])[cH:9][cH:10][c:11]21

Participants

5

Reactant 4

HCID 8471TriethylamineHCID 30165Iodide IonHCID 66111TrimethylsilylacetyleneHCID 107533577-Bromo-4,4-dimethyl-1,2,3,4-tetrahydronaphthalen-1-one

Product 1

HCID 106121314,4-Dimethyl-7-((trimethylsilyl)ethynyl)-3,4-dihydronaphthalen-1(2H)-one

Sources & evidence

ORD record
ord-987c4c6b15144ed2b0e30b19a3365056
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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