Chloroform → HCID 86737442, compound

HRID 1413216Notes

Reaction equation

[C:1]1([P:7](=O)([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(Cl)([Cl:23])=O.[CH:25]([Cl:28])([Cl:27])[Cl:26]>>[Cl-:23].[Cl-:26].[C:14]1([P:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[CH:25]([Cl:28])([Cl:27])[Cl:26]

Participants

Reactant 3

HCID 6212Chloroform

HCID 6371Phosgene

HCID 13097Triphenylphosphine Oxide

Product 1

HCID 86737442HCID 86737442, compound

Procedure

In accordance with the invention, triphenylphosphine oxide is reacted with phosgene in chloroform to form a triphenylphosphine dichloride-chloroform adduct. The resulting adduct is reduced with hydrogen to form the desired triphenylphosphine. The reduction may proceed in chloroform as a solvent or in the absence of a solvent.

Sources & evidence

ORD record: ord-3094e1c3ae334dd798d8b5ba69b1b57c
Source dataset: uspto-grants-1981_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04249023

Reaction notes

Loading…