Toluene → barium bis(nonylphenolate)

HRID 1413956Notes

Reaction equation

HRID 1413956 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[CH:11]=[CH:12][C:13](O)=[CH:14][CH:15]=1.C1(C)C=CC=CC=1.[O-2:24].[Ba+2:25].[Ba]>O.C(O)CCCCCCC>[CH2:9]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=1[O-:24])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1].[Ba+2:25].[CH2:9]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=1[O-:24])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

7

Reactant 4

HCID 1140TolueneHCID 17524-NonylphenolHCID 5355457BariumHCID 9855530Barium Oxide Nanoparticle Dispersion

Product 1

HCID 14029936barium bis(nonylphenolate)

Reagents, catalysts & solvents 2

HCID 9571-OctanolSolventHCID 962WaterSolvent

Procedure

Nonylphenol 110 g (0.5 mole), toluene 80 g, octanol 20 g and barium oxide 115 g (0.75 mole) were stirred and treated with 13.5 g water. Reaction proceeded with exothermic heat, and was continued nder reflux for 1 hour. After cooling, the mixture was filtered and there was obtained a black-green liquid overbased barium nonylphenolate complex, which was analyzed to find barium: 28% metal ratio:6.

Workup

  1. customReaction
  2. temperaturereflux for 1 hour
  3. temperatureAfter cooling
  4. filtrationthe mixture was filtered
  5. customthere was obtained a black-green liquid overbased barium nonylphenolate complex, which

Sources & evidence

ORD record
ord-dd22d70c304d44fbadcd774c399558e1
Source dataset
uspto-grants-1981_02
Patent number
US04252698

Reaction notes

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