1-Iodopropane → HCID 21486852, compound

HRID 1414236Notes

Reaction equation

HRID 1414236 reaction equation
[K].[O:2]1[C:6]([C:7]([O:9][CH2:10][CH3:11])=[O:8])=[N:5][NH:4][C:3]1=[S:12].[CH2:13](I)[CH2:14][CH3:15]>[Hg]>[CH2:13]([S:12][C:3]1[O:2][C:6]([C:7]([O:9][CH2:10][CH3:11])=[O:8])=[N:5][N:4]=1)[CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 336431-IodopropaneHCID 88082025HCID 88082025, compound

Product 1

HCID 21486852HCID 21486852, compound

Reagents, catalysts & solvents 1

HCID 23931MercuryCatalyst

Procedure

The title compound was prepared from ethyl 1,3,4-oxadiazole-2-thione-5-carboxylate potassium salt dimethylsulfoxide solvate (10 g., 28.5 mmole) and n-propyliodide (4.17 ml., 42.8 mmole) analogously to the procedure described in Experiment A. The yield was 4.99 g. (81%). The product had a B.P. of 108°-118° C. at 0.65 mm. of mercury.

Sources & evidence

ORD record
ord-ce871bc2435744269d4168792573e8ce
Source dataset
uspto-grants-1977_01
Patent number
US04001238

Reaction notes

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