2-Methyl-1-butene → HCID 131721832, compound

HRID 1420462Notes

Reaction equation

HRID 1420462 reaction equation
[CH3:1][C:2]([CH2:4][CH3:5])=[CH2:3].[CH2:6]([OH:82])[C@H:7]1[O:12][C@@H:11]2[O:13][C@H:14]3[C@H:19]([OH:20])[C@@H:18]([OH:21])[C@@H:17]([O:22][C@H:23]4[C@H:28]([OH:29])[C@@H:27]([OH:30])[C@@H:26]([O:31][C@H:32]5[C@H:37]([OH:38])[C@@H:36]([OH:39])[C@@H:35]([O:40][C@H:41]6[C@H:46]([OH:47])[C@@H:45]([OH:48])[C@@H:44]([O:49][C@H:50]7[C@H:55]([OH:56])[C@@H:54]([OH:57])[C@@H:53]([O:58][C@H:59]8[C@H:65]([OH:66])[C@@H:64]([OH:67])[C@@H:62]([O:63][C@H:8]1[C@H:9]([OH:81])[C@H:10]2[OH:80])[O:61][C@@H:60]8[CH2:68][OH:69])[O:52][C@@H:51]7[CH2:70][OH:71])[O:43][C@@H:42]6[CH2:72][OH:73])[O:34][C@@H:33]5[CH2:74][OH:75])[O:25][C@@H:24]4[CH2:76][OH:77])[O:16][C@@H:15]3[CH2:78][OH:79]>>[CH2:72]([OH:73])[C@H:42]1[O:43][C@@H:44]2[O:49][C@H:50]3[C@H:55]([OH:56])[C@@H:54]([OH:57])[C@@H:53]([O:58][C@H:59]4[C@H:65]([OH:66])[C@@H:64]([OH:67])[C@@H:62]([O:63][C@H:8]5[C@H:9]([OH:81])[C@@H:10]([OH:80])[C@@H:11]([O:13][C@H:14]6[C@H:19]([OH:20])[C@@H:18]([OH:21])[C@@H:17]([O:22][C@H:23]7[C@H:28]([OH:29])[C@@H:27]([OH:30])[C@@H:26]([O:31][C@H:32]8[C@H:37]([OH:38])[C@@H:36]([OH:39])[C@@H:35]([O:40][C@H:41]1[C@H:46]([OH:47])[C@H:45]2[OH:48])[O:34][C@@H:33]8[CH2:74][OH:75])[O:25][C@@H:24]7[CH2:76][OH:77])[O:16][C@@H:15]6[CH2:78][OH:79])[O:12][C@@H:7]5[CH2:6][OH:82])[O:61][C@@H:60]4[CH2:68][OH:69])[O:52][C@@H:51]3[CH2:70][OH:71].[CH3:3][C:2]([CH2:4][CH3:5])=[CH2:1]

Participants

3

Reactant 2

HCID 112402-Methyl-1-buteneHCID 444041beta-Cyclodextrin

Product 1

HCID 131721832HCID 131721832, compound

Procedure

100 ml of saturated β-cyclodextrin solution (1.8%) were cooled to 10° and mixed with 3 ml of 2-methyl-1-butene. The resulting difficultly soluble complex was precipitated with constant stirring in the ultrasonic bath. The deposit was obtained in crystalline form through freeze-drying and filtering. 2-methyl-1-butene content according to GC calculation: 0.82%

Workup

  1. customThe resulting difficultly soluble complex was precipitated
  2. customThe deposit was obtained in crystalline form
  3. customthrough freeze-drying
  4. filtrationfiltering

Sources & evidence

ORD record
ord-89bf25c01dcc47db98a6be430c53d472
Source dataset
uspto-grants-2000_06
Patent number
US06071496

Reaction notes

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