HRID1421337

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1004

Phosphoric acid

H3O4P

结构：O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ce+3]

HCID24948

Cerium trinitrate

CeN3O9

结构：O.O.[O]=[Al][O][Si](=O)O[Si](=O)[O][Al]=[O]

HCID56841936

未命名化合物

结构：O=C([O-])C(=O)[O-].O=C([O-])C(=O)[O-].O=C([O-])C(=O)[O-].O=C([O-])C(=O)[O-].O=C([O-])C(=O)[O-].[V+5].[V+5]

HCID178526029

未命名化合物

PRODUCTS

生成物

结构：O=P([O-])([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ce+3]

HCID86755301

未命名化合物

HCID178526029

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

A clay/phosphate/cerium nitrate, vanadium oxalate slurry was prepared by adding 1340 grams of Theile RC-32® kaolin clay slurry to 1795 milliliters of water in a high speed mixer. To this mixture, 192 grams of phosphoric acid was added. Thereafter, 431 grams of cerium nitrate solution and 232 grams of vanadium oxalate solution were added to the slurry. The slurry was then spray dried and then resulting particles were calcined at 650° C. for 30 minutes in a muffle furnace. The calcined particles were then mixed with magnesium oxide in a 50/50 weight percent ratio and analyzed by TGA tests. These tests indicated that the resulting material produced an SOx absorption of 0.27% per minute.

WORKUP

后处理

customThe slurry was then spray dried
additionThe calcined particles were then mixed with magnesium oxide in a 50/50 weight percent ratio
customproduced
customan SOx absorption of 0.27% per minute

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-cb4af3e3c8fb489bb52a91cf4a81a31b
来源数据集: uspto-grants-2000_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06074984
来源说明: uspto-grants-2000_06

反应 SMILES

O.O.O=[Al]O[Si](O[Si](O[Al]=O)=O)=O.[P:14](=[O:18])([OH:17])([OH:16])[OH:15].[N+:19]([O-:22])([O-:21])=[O:20].[Ce+3:23].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[C:32]([O-:37])(=[O:36])[C:33]([O-:35])=[O:34].[V+5:38].[C:39]([O-:44])(=[O:43])[C:40]([O-:42])=[O:41].[C:45]([O-:50])(=[O:49])[C:46]([O-:48])=[O:47].[C:51]([O-:56])(=[O:55])[C:52]([O-:54])=[O:53].[C:57]([O-:62])(=[O:61])[C:58]([O-:60])=[O:59].[V+5]>O>[P:14]([O-:18])([O-:17])([O-:16])=[O:15].[N+:19]([O-:22])([O-:21])=[O:20].[Ce+3:23].[N+:19]([O-:22])([O-:21])=[O:20].[N+:19]([O-:22])([O-:21])=[O:20].[C:32]([O-:37])(=[O:36])[C:33]([O-:35])=[O:34].[V+5:38].[C:39]([O-:44])(=[O:43])[C:40]([O-:42])=[O:41].[C:45]([O-:50])(=[O:49])[C:46]([O-:48])=[O:47].[C:51]([O-:56])(=[O:55])[C:52]([O-:54])=[O:53].[C:57]([O-:62])(=[O:61])[C:58]([O-:60])=[O:59].[V+5:38]