(1-Chloroethyl)benzene → HCID 178461712, compound

HRID 1422370Notes

Reaction equation

HRID 1422370 reaction equation
Br/C=C/CCOCc1ccccc1.CC(Cl)c1ccccc1>CC(=O)N(C)C.COCCOC.[Cl][Ni][Cl].[I-].[Na+].c1ccc2c(c1)C[C@@H]1OC(C3(C4=N[C@@H]5c6ccccc6C[C@@H]5O4)CC3)=N[C@H]21>C[C@@H](/C=C/CCOCc1ccccc1)c1ccccc1

Participants

7

Reactant 2

HCID 12648(1-Chloroethyl)benzeneHCID 14170983[(E)-4-bromobut-3-enoxy]methylbenzene

Product 1

HCID 178461712HCID 178461712, compoundYield 75%

Reagents, catalysts & solvents 4

HCID 5238Sodium IodideReagentHCID 11245230(3aR,3a'R,8aS,8a'S)-2,2'-(Cyclopropane-1,1-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole)CatalystHCID 15773433Dichloronickel;1,2-dimethoxyethaneCatalystHCID 31374DimethylacetamideSolvent

Conditions

Temperature
0 °C

Workup

  1. additionNo procedure recorded
  2. additionNo procedure recorded
  3. extractionKeep organic
  4. additionNo procedure recorded
  5. extractionKeep organic
  6. additionNo procedure recorded
  7. extractionKeep organic
  8. washNo procedure recorded
  9. dry with materialNo procedure recorded
  10. filtrationKeep filtrate
  11. concentrationNo procedure recorded

Sources & evidence

ORD record
ord-6f58b9fc4228408184023447b55ae3a4
Source dataset
Electroreductive Coupling of Alkenyl and Benzyl Halides
Original link
View source

Reaction notes

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