Acetate → HCID 178475931, compound

HRID 142672Notes

Reaction equation

HRID 142672 reaction equation
[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:37][O:38][C:39]([CH3:40])=[O:41])[O:7][CH:8]([c:19]2[cH:20][c:21]([CH2:26][c:27]3[cH:28][c:29]4[c:30]([cH:35][cH:36]3)[O:31][CH2:32][CH2:33][O:34]4)[c:22]([Br:25])[cH:23][cH:24]2)[CH:9]([O:15][C:16]([CH3:17])=[O:18])[CH:10]1[O:11][C:12]([CH3:13])=[O:14].[CH3:67][c:68]1[cH:69][cH:70][cH:71][cH:72][cH:73]1.[CH:42]1([P:43]([CH:47]2[CH2:48][CH2:49][CH2:50][CH2:51][CH2:52]2)[CH:55]2[CH2:46][CH2:45][CH2:44][CH2:59][CH2:60]2)[CH2:53][CH2:54][CH2:56][CH2:57][CH2:58]1.[CH:61]1([B:62]([OH:63])[OH:64])[CH2:65][CH2:66]1.[O-:76][C:77]([CH3:78])=[O:79].[O-:80][C:81]([CH3:82])=[O:83].[OH2:74].[Pd+2:75]>>[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:37][O:38][C:39]([CH3:40])=[O:41])[O:7][CH:8]([c:19]2[cH:20][c:21]([CH2:26][c:27]3[cH:28][c:29]4[c:30]([cH:35][cH:36]3)[O:31][CH2:32][CH2:33][O:34]4)[c:22]([CH:59]3[CH2:55][CH2:60]3)[cH:23][cH:24]2)[CH:9]([O:15][C:16]([CH3:17])=[O:18])[CH:10]1[O:11][C:12]([CH3:13])=[O:14]

Participants

8

Reactant 7

HCID 175Acetate2×HCID 962WaterHCID 1140TolueneHCID 75806TricyclohexylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2760897Cyclopropylboronic acidHCID 75951842HCID 75951842, compound

Product 1

HCID 178475931HCID 178475931, compound

Sources & evidence

ORD record
ord-21d01532bc4c444bb4871afa1655f8ef
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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