Benzene → 2-Methyl-1-phenyl-2-propen-1-one

HRID 1428433Notes

Reaction equation

HRID 1428433 reaction equation
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:11])[C:8]([CH3:10])=[CH2:9].[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:11])[C:8]([CH3:10])=[CH2:9]

Participants

5

Reactant 3

HCID 241BenzeneHCID 13528Methacryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 2636662-Methyl-1-phenyl-2-propen-1-one

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

Benzene (1 mL), methacryloyl chloride (0.156 mg), and aluminium chloride (199 mg) were reacted in carbon disulfide (2 mL) at from 0° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (106 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-1db898b1c6e94443a386b9da369b089f
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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