Bromobenzene → HCID 13245048, compound

HRID 1428437Notes

Reaction equation

HRID 1428437 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:8](Cl)(=[O:12])[C:9]([CH3:11])=[CH2:10].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:12])[C:9]([CH3:11])=[CH2:10])=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7961BromobenzeneHCID 13528Methacryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 13245048HCID 13245048, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Bromobenzene (0.5 mL), methacryloyl chloride (110 mg), and aluminium chloride (150 mg) were reacted in dichloromethane (1.5 mL) at from −20° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (1207 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-e7bd70683b0c46a2975651cf9125ba5b
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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