N-vinyl-2-pyrrolidone → HCID 86735186, compound

HRID 1438948Notes

Reaction equation

HRID 1438948 reaction equation
[CH:1]([N:3]1[CH2:7][CH2:6][CH2:5][C:4]1=[O:8])=[CH2:2].[C:9]([O:22][CH:23]=[CH2:24])(=[O:21])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]>CO.N(C(C)(C)C#N)=NC(C)(C)C#N>[CH:1]([N:3]1[CH2:7][CH2:6][CH2:5][C:4]1=[O:8])=[CH2:2].[C:9]([O:22][CH:23]=[CH2:24])(=[O:21])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

Participants

5

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 75069Vinyl laurate

Product 1

HCID 86735186HCID 86735186, compound

Reagents, catalysts & solvents 2

HCID 6547AzobisisobutyronitrileCatalystHCID 887MethanolSolvent

Conditions

Temperature
60 °C

Procedure

To a solution of 27.75 gm (0.25 mol) of N-vinylpyrrolidone and 169.5 gm (0.75 mol) of vinyl laurate in 460 gm of methanol were added 6 gm of azobisisobutyronitrile as catalyst. The resulting reaction mixture was agitated for 6 hours at 60° C, during which time the copolymer precipitated. After completion of the reaction, the methanol was distilled off and the polymer was washed a few times with fresh methanol. The yield was 176.5 gm (90% of theory) of N-vinylpyrrolidone/vinyl laurate copolymer (1:3 molar ratio).

Workup

  1. customThe resulting reaction mixture
  2. customprecipitated
  3. customAfter completion of the reaction
  4. distillationthe methanol was distilled off
  5. washthe polymer was washed a few times with fresh methanol

Sources & evidence

ORD record
ord-0be464ebc07c467e97ceae4a67568250
Source dataset
uspto-grants-1977_11
Patent number
US04057625

Reaction notes

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