Nitromethane → 25963-52-4

HRID 1441383Notes

Reaction equation

HRID 1441383 reaction equation
[SH-:1].[C+4:2].[SH-:3].[SH-].[SH-].[OH-].[K+:7].[N+:8]([CH3:11])([O-:10])=[O:9]>>[N+:8]([CH:11]=[C:2]([S-:3])[S-:1])([O-:10])=[O:9].[K+:7].[K+:7]

Participants

4

Reactant 3

HCID 6375NitromethaneHCID 14797Potassium HydroxideHCID 178420937HCID 178420937, compound

Product 1

HCID 1356369625963-52-4

Procedure

A mixture of nitromethane and carbon bisulfide dissolved in alcohols is added dropwise to the solution of potassium hydroxide in alcohol at room temperature. The reaction is carried out at the temperature range of 0-35° C. for 2-10 hours. The solid is filtered out to afford a crude product potassium 2-nitroethene-1,1-bis(thiolate) which is a brown yellow powder.

Workup

  1. filtrationThe solid is filtered out

Sources & evidence

ORD record
ord-49af9c59a3674e97bbe0909755d6ffb4
Source dataset
uspto-grants-2010_02
Patent number
US07655665B2

Reaction notes

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