Hydroxylamine sulfate → HCID 178508839, compound

HRID 1447173Notes

Reaction equation

HRID 1447173 reaction equation
[NH:1]=[C:2]1[C:10]2[C:5](=[C:6]([Cl:14])[C:7]([Cl:13])=[C:8]([Cl:12])[C:9]=2[Cl:11])[C:4](=[NH:15])[NH:3]1.S([O-])([O-])(=O)=[O:17].O[NH3+].O[NH3+]>CN(C)C=O>[N:15](=[C:4]1[C:5]2[C:10](=[C:9]([Cl:11])[C:8]([Cl:12])=[C:7]([Cl:13])[C:6]=2[Cl:14])[C:2](=[NH:1])[NH:3]1)[OH:17]

Participants

4

Reactant 2

HCID 24846Hydroxylamine sulfateHCID 178508680HCID 178508680, compound

Product 1

HCID 178508839HCID 178508839, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

28.3 Parts, 1,3-diimino-4,5,6,7-tetrachloro-isoindoline and 8.5 parts hydroxyl-ammonium sulphate are stirred in 150 parts dimethylformamide for 1 hour at 80°. After cooling the product can be filtered and washed with dimethylformamide and water to obtain pure 1-oximino-3-imino-4,5,6,7-tetrachloroisoindoline in the form of colourless crystalls which up to 300° only darken but do not melt.

Workup

  1. temperatureAfter cooling the product
  2. filtrationcan be filtered
  3. washwashed with dimethylformamide and water

Sources & evidence

ORD record
ord-f7965928648546b3b66db725389a088a
Source dataset
uspto-grants-1982_02
Patent number
US04316032

Reaction notes

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